Chemical Engineering GATE 2018 Questions with Answer

Ques 1 Chemical Reaction Engineering


Liquid phase isomerization of o-xylene to p-xylene using a zeolite catalyst was carried out in a CSTR. Three sets of kinetic data at different temperatures and stirring speeds were obtained as shown below.

The operating condition at which the reaction rate is not controlled by external mass transfer resistance is

A

T=500 K; rpm=3000

B

T=600 K; rpm=1000

C

(Π‘) T=700 K; rpm=1000

D

T=700 K; rpm=2000


Ques 2 Chemical Reaction Engineering


The reactant (M) is converted into product (N) in the presence of catalyst in a fixed bed reactor. All the flow rates (F, G, H, P and R) in mol/s, and mole fraction of reactant (M) in these streams (xF, xG, xH, xP and xR) are shown in the diagram.

The overall fractional conversion is

A

(xGG-xHH)/(xGG)

B

(xGG-xPP)/(xGG)

C

(xFF-xHH)/(xFF)

D

(xFF-xPP)/(xFF)


Ques 3 Chemical Reaction Engineering


For a chemical reaction, the ratio of rate constant at 500 K to that at 400 K is 2.5. Given R = 8.314 J mol-1 K-1, the value of activation energy (in kJ/mol) is

A

10.5

B

12.0

C

15.2

D

18.4


Ques 4 Chemical Reaction Engineering


The ammonia (NH3) oxidation process occurs over a catalyst as:
4 NH3 + 5 O2 β†’ 4 NO + 6 H2O
Air is supplied such that oxygen (O2) is 20% in excess of that required for complete conversion of NH3.
The mole fraction of O2 in the inlet gas mixture (NH3 + air) is ______ (rounded off to third decimal place).

0.185 is the correct answer.


Ques 5 Chemical Reaction Engineering


In a laboratory batch setup, reaction of P over a catalyst was studied at various temperatures.
The reactions occurring are:
P → 2Q
P → R

At the end of one hour of operation, the batch contains xP, xQ, and xR mole fractions of P, Q, and R components, respectively.
The mole fractions of product components (xQ and xR) were found to vary linearly with temperature as given in the figure.

If the yield of Q based on reactant P consumed (YQ) at 25 °C was found to be 0.40, then the value of YQ at 60 °C is ____________ (rounded off to second decimal place).

0.40 is the correct answer.


Ques 6 Chemical Reaction Engineering


A CSTR and a PFR of equal volume are connected in series as shown below to carry out a first-order, isothermal, liquid phase reaction

The rate constant is 0.2 s-1. The space-time is 5 s for both the reactors. The overall fractional conversion of A is ____________ (rounded off to third decimal place).

0.811 is the correct answer.


Ques 7 Chemical Reaction Engineering


The elementary second-order liquid phase reaction A + B β†’ C + D is carried out in an isothermal plug flow reactor of 2 m3 volume. The inlet volumetric flow rate is 10 m3/h. The initial concentrations of both A and B are 2 kmol/m3. The rate constant is given as 2.5 m3 kmol-1 h-1. The percentage conversion of A is ____________.

50 is the correct answer.


Ques 8 Chemical Reaction Engineering


A set of standard stainless steel pipes, each of internal diameter 26.65 mm and 6000 mm length, is used to make a plug flow reactor by joining them in series to carry out degradation of polyethylene. Seven such pipes are required to obtain a conversion of 66% at 450 K. The minimum number of standard 8000 mm long pipes of the same internal diameter to be procured for obtaining at least 66% conversion under the same reaction conditions is ___________.

6 is the correct answer.


Ques 9 Chemical Reaction Engineering


Hydrogenation of benzene is to be carried out using Ni (density = 8910 kg/m3) as catalyst, cast in the form of non-porous hollow cylinders, as shown below. The reaction occurs on all the surfaces of the hollow cylinder. During an experiment, one such cylinder is suspended in the reactant stream. If the observed rate of reaction is 0.39 mol (m2 of catalyst surface)-1 min-1, then the rate of reaction in mol (kg of catalyst)-1 min-1 is _____________ (rounded off to three decimal places).

0.039 is the correct answer.


Ques 10 Chemical Technology


In connection with petroleum refining, identify the incorrect statement among the following options.

A

Desalting of crude oil is done before processing it in atmospheric distillation unit

B

A stream of hydrogen is produced in catalytic reforming of naphtha

C

Asphalt used for paving is a petroleum product

D

Cetane number indicates the quality of petrol / motor spirit


Ques 11 Chemical Technology


Polyvinyl chloride is produced by

A

co-polymerization

B

addition-type kinetics

C

reacting chlorine with polyethylene

D

reacting hydrochloric acid with polyethylene


Ques 12 Chemical Technology


The molecular formula of the predominant chemical compound in commercial sugar is

A

C12H22O11

B

C12H24O12

C

C6H10O5

D

C6H12O6


Ques 13 Chemical Technology


Choose the correct statement
In viscose rayon manufacturing process,

A

carbon disulphide used as reactant for xanthate formation is regenerated in a later step

B

caustic soda used as reactant for steeping of cellulose is regenerated in a later step

C

sulphuric acid is used in steeping process of cellulose

D

the spun viscose rayon is hardened in an alkali bath


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